A greener, simpler way to create syngas

January 7, 2020 by Matthew Chin, University of California, Los Angeles
Schematic showing the atomic structure of the copper-ruthenium nanoparticle catalyst. Credit: John Mark Martirez/UCLA

Researchers from UCLA Samueli School of Engineering, Rice University and UC Santa Barbara have developed an easier and greener way to create syngas.

A study detailing their work is published today in Nature Energy.

Syngas (the term is short for "") is a mixture of carbon monoxide and hydrogen gases. It is used to make ammonia, methanol, other industrial chemicals and fuels. The most common process for creating syngas is coal gasification, which uses steam and oxygen (from air) at high temperatures, a process that produces large amounts of carbon dioxide.

One more environmentally friendly way to create syngas, called methane dry reforming, involves getting two potent greenhouse gases to react—methane (for example, from natural gas) and carbon dioxide. But that process is not widely used at industrial scales, partly because it requires temperatures of at least 1,300 degrees Fahrenheit (700 degrees Celsius) to initiate the reaction.

Over the past decade, researchers have tried to improve the process for creating syngas using various metal alloys that could catalyze the required chemical reaction at lower temperatures. But the tests were either inefficient or resulted in the being covered in coke, a residue of mostly carbon that builds up during the process.

In the new research, engineers found a more suitable catalyst: copper with a few atoms of the precious metal ruthenium exposed to visible light. Shaped like a tiny bump about 5 nanometers in diameter (a nanometer is one-billionth of a meter) and lying on top of a metal-oxide support, the new catalyst enables a chemical reaction that selectively produces syngas from the two greenhouse gases using visible light to drive the reaction, without requiring any additional thermal energy input.

In addition, in principle, the process requires only concentrated sunlight, which also prevents the buildup of coke that plagued earlier methods.

"Syngas is used ubiquitously in the to create many chemicals and materials that enable our ," said Emily Carter, a UCLA distinguished professor of chemical and biomolecular engineering, and a corresponding author of the paper. "What's exciting about this new process is that it offers the opportunity to react captured greenhouse gases—reducing emissions to the atmosphere—while creating this critical chemical feedstock using an inexpensive catalyst and renewable energy in the form of sunlight instead of using fossil fuels."

More information: Linan Zhou et al. Light-driven methane dry reforming with single atomic site antenna-reactor plasmonic photocatalysts, Nature Energy (2020). DOI: 10.1038/s41560-019-0517-9

Journal information: Nature Energy

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